Chemistry 51B: Organic Chemistry
Chemistry 51B: Organic Chemistry (Winter 2013, UC Irvine). Instructor: Professor David Van Vranken. This is the second quarter of the organic chemistry series. Topics covered include: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds.
Lecture 20 - Radicals |
Time | Lecture Chapters |
[00:00:00] | 1. Pycnogenol |
[00:00:42] | 2. What is Pycnogenol? |
[00:01:11] | 3. Molecular Structure of Pycnogenol |
[00:03:22] | 4. Ch 14.8: Splitting by More than One Type of Proton |
[00:07:55] | 5. Ch 14.9: Time Dependence of H NMR Spectroscopy-Bond Rotation |
[00:09:42] | 6. Ch 14.9: Time Dependence of H NMR Spectroscopy |
[00:15:37] | 7. Ch 15.1: Radicals-Reactivity and Stability |
[00:21:04] | 8. Ch 15.1, 15.2: Reactions of Radicals-a Specialized Arrow Symbol |
[00:24:55] | 9. Ch 15.3, 15.6, 15.7: Selective Conversion of Tertiary R-H to Tertiary R-Br |
[00:29:35] | 10. Ch 15.4: Mechanism for Radical Bromination |
[00:36:26] | 11. Ch 15.8: Carbon Radicals React on either End of the p Orbital |
[00:42:15] | 12. Ch 15.10: Allylic Bromination |
[00:48:06] | 13. Ch 15.13: Anti-Markovnikov of HBr to H2C=CHR |
[00:50:39] | 14. Chapter 15-Radical Summary |
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