Lecture 05 - Solvation, H-Bonding, and Ionophores. Most organic reactions occur in solution, and particularly in the case of ions, one must consider non-bonded interactions
with neighboring molecules. Non-bonded interactions, including hydrogen-bonding, also determine such physical properties as boiling point. For the most part these interactions may be
understood in terms of electrostatics and polarizability. Artificial or natural ion carriers (ionophores) can be tailored to bind specific ions. Energetically the ionic dissociation of
water in the gas phase is prohibitively expensive. (from oyc.yale.edu)
Lecture 05 - Solvation, H-Bonding, and Ionophores
Time
Lecture Chapters
[00:00:00]
1. Puzzle on Alcohol Oxidation Mechanisms
[00:02:58]
2. Solvation, Boiling Points, and "Intramolecular Solvation"
[00:11:45]
3. Solvophobic Forces and Hydrogen-Bonding
[00:28:09]
4. Ionophores and Phase-Transfer Catalysis
[00:45:05]
5. Energetics of Gas-Phase Heterolysis
References
Lecture 5 - Solvation, H-Bonding, and Ionophores
Instructor: Professor J. Michael McBride. Resources: Professor McBride's website resource for CHEM 125b (Spring 2011). Transcript [html]. Audio [mp3]. Download Video [mov].